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Comparison of Sector Interim Recommendations or Preferred Options - 23 February 2006

Physical Hazards

Explosive

Division 1.1 1.2 1.3 1.4 1.5 1.6
GHS Explosive
Danger

Explosive; mass explosion hazard
Explosive
Danger

Explosive; severe projection hazard
Explosive
Danger

Explosive; fire, blast
or
projection hazard


No Symbol

Warning

Fire or projection hazard


No Symbol

Warning

May explode in fire
 
CC* No No No No No No
PCP Yes Yes Yes Yes Yes Yes
TDG Yes Yes Yes Yes Yes Yes
WHMIS Not yet discussed Not yet discussed Not yet discussed Not yet discussed Not yet discussed Not yet discussed

*Explosives are exempt from the Hazardous Products Act (Part I)

Flammable Gases

Division Category 1 Category 2
GHS Flammable Gases
Danger

Extremely flammable gas


No Symbol

Warning

Flammable gas
CC Yes Yes
PCP Yes Yes
TDG Yes No
WHMIS Yes Yes

Flammable Aerosols

Division Category 1 Category 2
GHS Flammable Gases
Danger

Extremely flammable aerosol
Flammable Gases
Warning

Flammable aerosol
CC Yes Yes
PCP Yes Yes
TDG Yes Yes
WHMIS Yes Yes

Oxidizing Gases

Division Category 1
GHS Oxidizing
Danger

May cause or intensify fire; oxidizer
CC Not yet discussed
PCP Yes
TDG Yes
WHMIS* Yes

*For mixtures: The WHMIS Working Group recommended inclusion of the mathematical formula in the proposed amendment to the WHMIS regulations (Controlled Products Regulations) upon GHS implementation

Gases Under Pressure

Division Compressed Gas Liquified Gas Refrigerated Liquified Gas Dissolved Gas
GHS Gases Under Pressure
Warning

Contains gas under pressure; may explode if heated
Gases Under Pressure
Warning

Contains gas under pressure; may explode if heated
Gases Under Pressure
Warning

Contains refrigerated gas; may cause cryogenic burns or injury
Gases Under Pressure
Warning

Contains gas under pressure; may explode if heated
CC Yes Yes Yes Yes
PCP Yes Yes Yes Yes
TDG Yes Yes Yes Yes
WHMIS Yes Yes Yes Yes

Flammable Liquids

Division Category 1 Category 2 Category 3 Category 4
GHS Flashpoint
<23°C
Initial Boiling Pt
≤35°C

Flammable Gases
Danger

Extremely flammable liquid and vapour
Flashpoint
<23°C
Initial Boiling Pt
>35°C

Flammable Gases
Danger

Highly flammable liquid and vapour
Flashpoint
≥23°C
and
≤60°C

Flammable Gases
Warning

Flammable liquid and vapour
Flashpoint
>60°C
and
≤93°C


No symbol


Warning

Combustible liquid
CC Yes Yes Yes No*
PCP Yes Yes Yes Yes
TDG Yes Yes Yes** No
WHMIS*** Yes Yes Yes Yes

*As per 28 June 2005 Consumer Chemical Sector Working Group meeting and comments

** The current TDG cut point for Category 3 is 60.50 C but this will be changed to 600 C in Amendment Schedule 6

*** For Mixtures: The WHMIS Current Issues Committee recommended that the mathematical formula not be included in the proposed amendments to the WHMIS regulations (Controlled Products Regulations) upon GHS implementation.

Flammable Solids

Division Category 1 Category 2
GHS Flammable Gases
Danger

Flammable solid
Flammable Gases
Warning

Flammable solid
CC Yes Yes
PCP Yes Yes
TDG Yes Yes
WHMIS Yes Yes

Self-Reactive Substances

Division Type A Type B Type C & D Type E & F Type G
GHS Explosive
Danger

Heating may cause an explosion
Flammable Gases
Explosive
Danger

Heating may cause a fire or explosion
Flammable Gases
Danger

Heating may cause a fire
Flammable Gases
Warning

Heating may cause a fire

No label elements
CC Not yet discussed Not yet discussed Not yet discussed Not yet discussed Not yet discussed
PCP Yes Yes Yes Yes Yes
TDG No* Yes Yes Yes No
WHMIS Yes Yes Yes Yes Pending additional information**

* Type A Self-Reactive substances are FORBIDDEN for Transport

** The WHMIS Working Group recommended revisiting self-reactive substances and ascertaining the rationale for inclusion of Type G products (i.e., no label elements).

Pyrophoric Liquids

Division Category 1
GHS Flammable Gases
Danger

Catches fire spontaneously if exposed to air
CC Not yet discussed
PCP Yes
TDG Yes
WHMIS Yes

Pyrophoric Solids

Division Category 1
GHS Flammable Gases
Danger

Catches fire spontaneously if exposed to air
CC Not yet discussed
PCP Yes
TDG Yes
WHMIS Yes

Self Heating Substances

Division Category 1 Category 2
GHS Flammable Gases
Danger

Self-heating; may catch fire
Flammable Gases
Warning

Self-heating in large quantities; may catch fire
CC Not yet discussed Not yet discussed
PCP Yes Yes
TDG Yes Yes
WHMIS Yes Yes

Substances, which in contact with water, emit flammable gases

Division Category 1 Category 2 Category 3
GHS Flammable Gases
Danger

In contact with water releases flammable gases which may ignite spontaneously
Flammable Gases
Danger

In contact with water releases flammable gases
Flammable Gases
Warning

In contact with water releases flammable gases
CC Not yet discussed Not yet discussed Not yet discussed
PCP Yes Yes Yes
TDG Yes Yes Yes
WHMIS Yes Yes Yes

Oxidizing Liquids

Division Category 1 Category 2 Category 3
GHS Oxidizing
Danger

May cause fire or explosion; strong oxidizer
Oxidizing
Danger

May intensify fire; oxidizer
Oxidizing
Warning

May intensify fire; oxidizer
CC Not yet discussed Not yet discussed Not yet discussed
PCP Yes Yes Yes
TDG Yes Yes Yes
WHMIS Yes Yes Yes

Oxidizing Solids

Division Category 1 Category 2 Category 3
GHS Oxidizing
Danger

May cause fire or explosion; strong oxidizer
Oxidizing
Danger

May intensify fire; oxidizer
Oxidizing
Warning

May intensify fire; oxidizer
CC Not yet discussed Not yet discussed Not yet discussed
PCP Yes Yes Yes
TDG Yes Yes Yes
WHMIS Yes Yes Yes

Organic Peroxides

Division Type A Type B Type C & D Type E & F Type G
GHS Explosive
Danger

Heating may cause an explosion
Explosive
Oxidizing
Danger

Heating may cause a fire or explosion
Oxidizing
Danger

Heating may cause a fire
Oxidizing
Warning

Heating may cause a fire

No label elements
CC Not yet discussed Not yet discussed Not yet discussed Not yet discussed Not yet discussed
PCP Yes Yes Yes Yes Yes
TDG No* Yes Yes Yes No
WHMIS Yes Yes Yes Yes Pending additional information **

*Type A organic peroxides are FORBIDDEN for Transport

** The WHMIS Working Group recommended revisiting organic peroxides and ascertaining the rationale for inclusion of Type G products (i.e., no label elements).

Corrosive to Metals

Division Category 1
GHS Corrosive
Warning

May be corrosive to metals
CC Not yet discussed
PCP Yes
TDG Yes
WHMIS Yes